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In1.08Gd0.92Ge2O7: a new member of the thortveitite family.

Identifieur interne : 003538 ( Main/Exploration ); précédent : 003537; suivant : 003539

In1.08Gd0.92Ge2O7: a new member of the thortveitite family.

Auteurs : RBID : pubmed:12359918

Abstract

Indium gadolinium digermanium heptaoxide, In(1.08)Gd(0.92)Ge(2)O(7), with a thortveitite-type structure, has been prepared as a polycrystalline powder material by a high-temperature solid-state reaction. As in the mineral thortveitite, the crystal structure belongs to the monoclinic system, with space group C2/m (No. 12). The precise structural parameters were obtained by applying the Rietveld method of refinement to the X-ray powder diffraction data. This layered structure presents, on one side, a honeycomb-like arrangement of the unique octahedral site, which is occupied randomly by In and Gd atoms, and, on the other side, sheets of isolated Ge(2)O(7) diortho-groups made up of double tetrahedra sharing a common vertex and displaying C(2h) point symmetry. This compound showed a remarkable photoluminescence effect when it was irradiated with the X-ray beam during the X-ray diffraction measurements, and with the alpha beam during the Rutherford back-scattering spectrometry experiments employed to analyze the chemical stoichiometry.

PubMed: 12359918

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Le document en format XML

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<name sortKey="Juarez Arellano, Erick Adrian" uniqKey="Juarez Arellano E">Erick-Adrian Juarez-Arellano</name>
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<nlm:affiliation>Instituto de Física, Universidad Nacional Autónoma de México, AP 20-364, 01000 México DF, Mexico.</nlm:affiliation>
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<name sortKey="Rosales, Ivonne" uniqKey="Rosales I">Ivonne Rosales</name>
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<name sortKey="Bucio, Lauro" uniqKey="Bucio L">Lauro Bucio</name>
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<name sortKey="Orozco, Eligio" uniqKey="Orozco E">Eligio Orozco</name>
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<div type="abstract" xml:lang="en">Indium gadolinium digermanium heptaoxide, In(1.08)Gd(0.92)Ge(2)O(7), with a thortveitite-type structure, has been prepared as a polycrystalline powder material by a high-temperature solid-state reaction. As in the mineral thortveitite, the crystal structure belongs to the monoclinic system, with space group C2/m (No. 12). The precise structural parameters were obtained by applying the Rietveld method of refinement to the X-ray powder diffraction data. This layered structure presents, on one side, a honeycomb-like arrangement of the unique octahedral site, which is occupied randomly by In and Gd atoms, and, on the other side, sheets of isolated Ge(2)O(7) diortho-groups made up of double tetrahedra sharing a common vertex and displaying C(2h) point symmetry. This compound showed a remarkable photoluminescence effect when it was irradiated with the X-ray beam during the X-ray diffraction measurements, and with the alpha beam during the Rutherford back-scattering spectrometry experiments employed to analyze the chemical stoichiometry.</div>
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